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Bioinorg Chem Appl. 2010:307696. doi: 10.1155/2010/307696. Epub 2010 Jun 10.

A synthetic approach of new trans-substituted hydroxylporphyrins.

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1
Laboratory of Bioinorganic Coordination Chemistry, Department of Chemistry, School of Sciences, University of Crete, P.O. Box 2208, Heraklion 71003, Crete, Greece.

Abstract

The synthesis of new trans A(2)B(2)-substituted porphyrins bearing oxygenic substituent (methoxy, acetoxy, hydroxy) at the periphery of the ring are described. All of the synthesized products were characterized by (1)H-N.M.R., (13)C-N.M.R., and H.R.M.S. Electrochemical studies revealed two one-electron oxidations and two reductions. In addition, the X-ray structure of one methoxy-derivative was determined.

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