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Chem Commun (Camb). 2004 Mar 7;(5):582-3. Epub 2004 Feb 3.

Direct epoxidation of propylene by molecular oxygen over a catalyst system containing palladium and a peroxo-heteropoly compound in methanol.

Author information

1
Research Institute for Green Technology, National Institute of Advanced Industrial Science and Technology, AIST Tsukuba Central 5, 1-1-1 Higashi, Tsukuba, Ibaraki 305-8565, Japan. yy.ryuu@aist.go.jp

Abstract

A catalyst system consisting of palladium and a peroxo-heteropoly compound in methanol showed 81.6% selectivity for propylene oxide at 42.7% propylene conversion using molecular oxygen as oxidant in an autoclave reactor at 373 K for 6 h.

PMID:
14973618
DOI:
10.1039/b316100p

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