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Items: 1 to 20 of 29

1.

Organolithium-Initiated Polymerization of Olefins in Deep Eutectic Solvents under Aerobic Conditions.

Sánchez-Condado A, Carriedo GA, Presa Soto A, Rodríguez-Álvarez MJ, García-Álvarez J, Hevia E.

ChemSusChem. 2019 Mar 20. doi: 10.1002/cssc.201900533. [Epub ahead of print]

PMID:
30892815
2.

Divergent Multistep Continuous Synthetic Transformations of Allylic Alcohol Enabled by Catalysts Immobilized in Ionic Liquid Phases.

Peris E, Porcar R, García-Álvarez J, Burguete MI, García-Verdugo E, Luis SV.

ChemSusChem. 2019 Apr 23;12(8):1684-1691. doi: 10.1002/cssc.201900107. Epub 2019 Mar 28.

PMID:
30803157
3.

The Future of Polar Organometallic Chemistry Written in Bio-Based Solvents and Water.

García-Álvarez J, Hevia E, Capriati V.

Chemistry. 2018 Oct 9;24(56):14854-14863. doi: 10.1002/chem.201802873. Epub 2018 Sep 20.

PMID:
29917274
4.

Introducing Glycerol as a Sustainable Solvent to Organolithium Chemistry: Ultrafast Chemoselective Addition of Aryllithium Reagents to Nitriles under Air and at Ambient Temperature.

Rodríguez-Álvarez MJ, García-Álvarez J, Uzelac M, Fairley M, O'Hara CT, Hevia E.

Chemistry. 2018 Feb 1;24(7):1720-1725. doi: 10.1002/chem.201705577. Epub 2018 Jan 15.

5.

AuI Iminophosphorane Complexes as Efficient Catalysts for the Cycloisomerization of Alkynyl Amides under Air, at Room Temperature, and in Aqueous or Eutectic-Mixture Solutions.

Rodríguez-Álvarez MJ, Vidal C, Schumacher S, Borge J, García-Álvarez J.

Chemistry. 2017 Mar 8;23(14):3425-3431. doi: 10.1002/chem.201605303. Epub 2017 Feb 7.

PMID:
28052449
6.

Exploiting Deep Eutectic Solvents and Organolithium Reagent Partnerships: Chemoselective Ultrafast Addition to Imines and Quinolines Under Aerobic Ambient Temperature Conditions.

Vidal C, García-Álvarez J, Hernán-Gómez A, Kennedy AR, Hevia E.

Angew Chem Int Ed Engl. 2016 Dec 23;55(52):16145-16148. doi: 10.1002/anie.201609929. Epub 2016 Nov 28.

7.

Special Issue: "Organic Reactions in Green Solvents".

Sperry J, García-Álvarez J.

Molecules. 2016 Nov 15;21(11). pii: E1527.

8.

From a Sequential to a Concurrent Reaction in Aqueous Medium: Ruthenium-Catalyzed Allylic Alcohol Isomerization and Asymmetric Bioreduction.

Ríos-Lombardía N, Vidal C, Liardo E, Morís F, García-Álvarez J, González-Sabín J.

Angew Chem Int Ed Engl. 2016 Jul 18;55(30):8691-5. doi: 10.1002/anie.201601840. Epub 2016 Jun 3.

PMID:
27258838
9.

Chemoenzymatic one-pot synthesis in an aqueous medium: combination of metal-catalysed allylic alcohol isomerisation-asymmetric bioamination.

Ríos-Lombardía N, Vidal C, Cocina M, Morís F, García-Álvarez J, González-Sabín J.

Chem Commun (Camb). 2015 Jul 11;51(54):10937-40. doi: 10.1039/c5cc03298a.

PMID:
26062926
10.

Introducing deep eutectic solvents as biorenewable media for Au(I)-catalysed cycloisomerisation of γ-alkynoic acids: an unprecedented catalytic system.

Rodríguez-Álvarez MJ, Vidal C, Díez J, García-Álvarez J.

Chem Commun (Camb). 2014 Nov 4;50(85):12927-9. doi: 10.1039/c4cc05904b.

PMID:
25215857
11.

Introducing deep eutectic solvents to polar organometallic chemistry: chemoselective addition of organolithium and Grignard reagents to ketones in air.

Vidal C, García-Álvarez J, Hernán-Gómez A, Kennedy AR, Hevia E.

Angew Chem Int Ed Engl. 2014 Jun 2;53(23):5969-73. doi: 10.1002/anie.201400889. Epub 2014 Apr 25.

12.

New Ag(I)-iminophosphorane coordination polymers as efficient catalysts precursors for the MW-assisted Meyer-Schuster rearrangement of propargylic alcohols in water.

García-Álvarez J, Díez J, Vidal C, Vicent C.

Inorg Chem. 2013 Jun 3;52(11):6533-42. doi: 10.1021/ic400511d. Epub 2013 May 15.

PMID:
23675864
13.

Synthesis and reactivity of new rhenium(I) complexes containing iminophosphorane-phosphine ligands: application to the catalytic isomerization of propargylic alcohols in ionic liquids.

García-Álvarez J, Díez J, Gimeno J, Seifried CM, Vidal C.

Inorg Chem. 2013 May 6;52(9):5428-37. doi: 10.1021/ic4003687. Epub 2013 Apr 17.

PMID:
23594134
14.

Novel rhenium(I) catalysts for the isomerization of propargylic alcohols into α,β-unsaturated carbonyl compounds: an unprecedented recyclable catalytic system in ionic liquids.

García-Álvarez J, Díez J, Gimeno J, Seifried CM.

Chem Commun (Camb). 2011 Jun 14;47(22):6470-2. doi: 10.1039/c1cc10768b. Epub 2011 May 9.

PMID:
21552615
15.

Structural basis for regioisomerization in the alkali-metal-mediated zincation (AMMZn) of trifluoromethyl benzene by isolation of kinetic and thermodynamic intermediates.

Armstrong DR, Blair VL, Clegg W, Dale SH, Garcia-Alvarez J, Honeyman GW, Hevia E, Mulvey RE, Russo L.

J Am Chem Soc. 2010 Jul 14;132(27):9480-7. doi: 10.1021/ja1038598.

16.

Structurally stimulated deprotonation/alumination of the TMP anion.

Conway B, Kennedy AR, Mulvey RE, Robertson SD, García Alvarez J.

Angew Chem Int Ed Engl. 2010 Apr 19;49(18):3182-4. doi: 10.1002/anie.201000181. No abstract available.

17.

Access to the first (iminophosphoranyl)(selenophosphoranyl)methane ligands Ph2P(=Se)CH2P(=NR)Ph2: coordination of their methanide and methandiide anions to ruthenium.

Cadierno V, Díez J, García-Alvarez J, Gimeno J.

Dalton Trans. 2010 Jan 21;39(3):941-56. doi: 10.1039/b916554a. Epub 2009 Nov 19.

PMID:
20066239
18.

Synthetic and structural insights into the zincation of toluene: direct synergic ring metallation versus indirect nonsynergic lateral metallation.

Armstrong DR, García-Alvarez J, Graham DV, Honeyman GW, Hevia E, Kennedy AR, Mulvey RE.

Chemistry. 2009;15(15):3800-7. doi: 10.1002/chem.200801928.

PMID:
19229931
19.
20.

Synthesis and characterisation of new bimetallic alkali metal-magnesium mixed diisopropylamide-acetylides: structural variations in bimetallic lithium- and sodium-heteroleptic magnesiates.

García-Alvarez J, Graham DV, Hevia E, Kennedy AR, Mulvey RE.

Dalton Trans. 2008 Mar 21;(11):1481-6. doi: 10.1039/b716215d. Epub 2008 Feb 14.

PMID:
18322628

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