Electrospun Nb₂O₅ nanorods/microporous multichannel carbon nanofiber film anode for Na⁺ ion capacitors with good performance

For the disadvantages of both the slow reaction kinetics and the poor conductivity for Nb₂O₅ electrode materials as sodium-ion capacitors (SICs), Nb₂O₅ NRs/NMMCNF film electrode with good flexibility and high electrochemical property has been fabricated by electrospinning PAN/PMMA/H₂Nb₂O₆·H₂O homogeneous viscous suspension and followed by an annealing treatment, in which the precursor H₂Nb₂O₆·H₂O nanorods are obtained by grinding H₂Nb₂O₆·H₂O nanowires, and Nb₂O₅ nanorods are uniformly embedded in nitrogen doped microporous multichannel carbon nanofiber. Benefiting from the multichannel network structure, Nb₂O₅ NRs/NMMCNF film electrode delivers the fast kinetics of Na⁺-storage and the superior Na-ion storage performance, it delivers outstanding rate capability (101 mAh g^-1 at 4 A g^-1) and ultralong lifespan (91% capacity retention after 10,000 cycles at 2 A g^-1). A Nb₂O₅ NRs/NMMCNF//AC SIC based on the Nb₂O₅ NRs@NMMCNF fiber film anode and the AC cathode is assembled. The energy density of the as-assembled device is as high as 91 Wh kg^-1 and its maximum power density is 7499 W kg^-1. This work offers a new structure design strategy toward intercalation-type metal oxide electrodes for application in SICs.