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Org Biomol Chem. 2019 Dec 28;17(48):10119-10141. doi: 10.1039/c9ob01994d. Epub 2019 Nov 20.

Recent advances in cobalt-catalysed C-H functionalizations.

Author information

1
Department of Chemistry, University of Pavia, Viale Taramelli 10, Pavia 27100, Italy. gz@unipv.it.
2
Department of Chemistry, Indian Institute of Technology Bombay, Powai, Mumbai 400076, India. dmaiti@iitb.ac.in.

Abstract

Ready availability, low cost and low toxicity of cobalt salts have redirected the attention of researchers away from noble metals, such as Pd, Rh, and Ir, towards Co in the field of C-H functionalization. In this context, the examples of Co-catalysed functionalization have exponentially grown over the last few decades. This present review focuses on the most recent developments on Co-catalysed C(sp2)-H and C(sp3)-H functionalizations. Included is also a comprehensive overview of enantioselective transformations.

PMID:
31746910
DOI:
10.1039/c9ob01994d

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