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Inorg Chem. 2019 Oct 7;58(19):12501-12505. doi: 10.1021/acs.inorgchem.9b01732. Epub 2019 Sep 10.

Assembly of Metal-Organic Frameworks of SiF62- in Situ Formed from Borosilicate Glass.

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College of Chemistry and Materials Science , Jinan University , Guangzhou 510632 , P. R. China.
Department of Chemistry , Shantou University , Guangdong 515063 , P. R. China.


The SiF62- anions are in situ formed in the reactions of MF2 (M = Cu2+, Zn2+, Ni2+, and Co2+) salts and nitrogen-containing ligands in borosilicate glass tubes under solvothermal conditions and then used to further construct a family of metal-organic frameworks (MOFs). This in situ reaction demonstrates a new and facile strategy for the fabrication of MOFs based on SiF62-.

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