Assessment of trends and emission sources of heavy metals from the soil sediments near the Bohai Bay

Anthropogenic emission sources (mainly vehicular and industrial emission) are one of the major emission sources of the heavy metals in aquatic ecosystems which have significant potential to perturb the marine geochemistry and ecosystem as well as human life also. In the present study, we tried to investigate the accumulation of heavy metals (Zn, Cr, Ni, Cu, Pb, Co, As, Cd, and Hg) at two sediment cores near the Bohai Bay in Southern Tianjin and reconstruct their historical trends over the last hundred years to understand the impacts of anthropogenic activities. The concentration of Zn and Cr is found maximum than the other studied heavy metals. Results suggest that in the mid-twentieth century, the maximum concentrations of Zn, Cr, Ni, Cu, and Pb are mainly because of the opening of Dagang Oilfield which emits a huge amount of heavy metals into the environment. Source apportionment analysis has been carried out using positive matrix factorization (PMF) model which suggests three major emission sectors of heavy metals, i.e., coal combustion, manufacturing, and smelting dust, having different contribution 32%, 40%, and 28% respectively to the total heavy metal burden. Industrial emissions are found to be the major sources of Cr, Ni, and Co while Pb is mainly originated from the coal combustion. The risk assessment analysis shows the value of mean effects range median (ERM) quotients ~ 0.17 for the two sediment cores which suggest nearly 21% toxicity of the studied metals indicating towards the policymakers for the mitigation of air pollution surrounding Tianjin.