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Org Biomol Chem. 2019 Jul 21;17(27):6612-6619. doi: 10.1039/c9ob01023h. Epub 2019 Jun 24.

Visible-light-induced deboronative alkylarylation of acrylamides with organoboronic acids.

Author information

1
Department of Chemistry, Huaibei Normal University, Huaibei, Anhui 235000, P.R. China. hanmy10@126.com wangmin204@chnu.edu.cn.
2
Department of Chemistry, Huaibei Normal University, Huaibei, Anhui 235000, P.R. China. hanmy10@126.com wangmin204@chnu.edu.cn and State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, P R China.

Abstract

A visible-light-induced deboronative alkylarylation of acrylamides with organoboronic acids was developed. In this transformation, boronic acids could be activated by the organic photocatalyst of eosin Y, generating alky free radicals in high efficiency. A broad range of substrate scope was examined and a number of 3,3-disubstituted oxindoles were synthesized in high yields.

PMID:
31231744
DOI:
10.1039/c9ob01023h

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