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Dalton Trans. 2019 Jul 21;48(27):9916-9919. doi: 10.1039/c9dt02032b. Epub 2019 Jun 14.

Ligand-directed assembly engineering of trapezoidal {Ti5} building blocks stabilized by dimethylglyoxime.

Author information

1
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences, Fuzhou, Fujian 350002, P. R. China. LZhang@fjirsm.ac.cn.

Abstract

Through ligand-directed assembly of trapezoidal {Ti5} building blocks stabilized by dimethylglyoxime, eight titanium-oxo molecular clusters with a sandwich or square planar type structures were successfully constructed, including the first success on the combination of porphyrin and titanium-oxo clusters.

PMID:
31199422
DOI:
10.1039/c9dt02032b

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