The dynamics governing the movement of the radon are complex and dependent on many factors. In the present study, we characterise the nature of temporal variations of 2-hourly and daily radon measurements in several monitoring sites of the Italian Radon mOnitoring Network (IRON) in Italy. By means of continuous wavelet transformation, a spectral analysis in time-frequency domain is performed. The results reveal that there are sub-daily, daily and yearly persistent periodicities that are common for all the stations. We observe structural seasonal breaks, that occur at the same frequency but at distinct time. Variations in radon concentration and local temperature are studied in terms of frequency contents and synchronicity. When analysing several long time series together, it is evident that the phase difference at low frequency movements (365-day period) between the radon and local temperature time series is depending on the sites' location and therefore strongly controlled by local factors. This could at least partially explain the apparently contrasting results available in the literature obtained investigating smaller dataset about the relationships between temperature and radon variations. On the other hand, results show that all radon time series are characterised by marked cycles at 1 and 365-days and less evident cycles at 0.5-day and 180-days. They would be all ascribable to environmental-climatic factors: the short-period cycles to temperature and pressure variations, the long-period cycles also to seasonal rainfall variations.