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Chem Commun (Camb). 2019 Jul 4;55(52):7562-7565. doi: 10.1039/c9cc03485d. Epub 2019 Jun 13.

Designing a new family of oxonium-cation based structurally diverse organic-inorganic hybrid iodoantimonate crystals.

Author information

1
Department of Physics and Centre for Energy Science, Indian Institute of Science Education and Research, Pune, Pune-411008, Maharashtra, India. mchenna@students.iiserpune.ac.in satishogale@iiserpune.ac.in and Department of Technology, Savitribai Phule Pune University, Ganeshkhind, Pune, Maharashtra 411007, India.
2
Department of Physics and Centre for Energy Science, Indian Institute of Science Education and Research, Pune, Pune-411008, Maharashtra, India. mchenna@students.iiserpune.ac.in satishogale@iiserpune.ac.in.
3
Department of Physics, Savitribai Phule Pune University, Ganeshkhind, Pune, Maharashtra 411007, India.
4
Discipline of Physics, Indian Institute of Technology, Indore-453552, Madhya Pradesh, India. sudiphys@gmail.com.

Abstract

Several new structurally diverse carbonyl functional group-based iodoantimonate organic-inorganic hybrid crystals are synthesized using an in situ formed oxonium cationic precursor. These crystals exhibit interesting optoelectronic properties consistent with DFT calculations. Charge transfer and photoluminescence quenching between these crystals and Au nanoparticulate films are examined for potential application interest.

PMID:
31190046
DOI:
10.1039/c9cc03485d

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