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Faraday Discuss. 2019 Jul 4;215(0):393-406. doi: 10.1039/c8fd00169c.

p-Type dye-sensitized solar cells based on pseudorotaxane mediated charge-transfer.

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Homogeneous Supramolecular and Bio-inspired Catalysis, Van't Hoff Institute for Molecular Sciences (HIMS), University of Amsterdam (UvA), Science Park 904, 1098 XH Amsterdam, The Netherlands.


The efficiency of p-type dye-sensitized solar cells (DSSCs) remains low compared to that of n-type congeners due to charge recombination events. We report a supramolecular approach to reduce recombination at the NiO-dye interface, realized by using the cyclophane cyclobis(paraquat-p-phenylene) ring (RING4+/RING3˙+) as a redox mediator and a dye (PN) functionalized with a 1,5-dioxynaphthalene (DNP) recognition site, promoting the supramolecular formation of a pseudorotaxane capable of directing charge transfer away from the NiO-dye interface. The binding affinity of RING4+ to PN is high (Kass = 3.4 × 104 M-1), with quenching of the photoexcited dye (PN*) ascribed to reduction of RING4+ to RING3˙+. The reduced RING3˙+ exhibits a lower binding affinity to PN, facilitating exchange with the excess RING4+ present in solution. This supramolecular phenomenon was implemented into p-type DSSCs by anchoring the PN dye on a NiO photocathode in conjunction with the RING4+/RING3˙+ redox couple, yielding a 10 fold enhancement in the short-circuit photocurrent (JSC) compared to control devices utilizing P1 dye or the methylviologen (MV2+/MV˙+) redox couple that cannot form pseudorotaxanes.


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