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Phys Chem Chem Phys. 2019 Jun 5;21(22):11599-11607. doi: 10.1039/c9cp00585d.

Homogeneous silver colloidal substrates optimal for metal-enhanced fluorescence.

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Department of Chemistry, Gwangju Institute of Science and Technology, 123 Cheomdangwagi-ro, Buk-gu, Gwangju 61005, Republic of Korea.


Homogeneous silver colloidal films (SCFs), composed of silver nanoparticles 67-193 nm in diameter, were synthesized by a seeded-growth method as the substrates for metal-enhanced fluorescence (MEF). The homogeneity and uniform particle distribution of the SCFs showed many advantages for the exploration of the MEF mechanism. The fluorescence enhancement of 4-(dicyanomethylene)-2-methyl-6-(4-dimethylaminostyryl)-4H-pyran (DCM) and rhodamine 700 (Rh700) dyes dispersed in a thin layer of polystyrene (PS) with the SCFs was observed by time-resolved fluorescence spectroscopy. The fluorescence enhancements of DCM and Rh700 become larger when the surface plasmon resonance bands of SCFs overlap the emission bands of dyes. The particle-size-dependent changes of the radiative and non-radiative rate constants of both dyes with the SCFs are estimated by an improved analysis combining the fluorescence intensity and lifetime measurements and the finite-difference time-domain method simulations.


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