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Chem Commun (Camb). 2019 Apr 2;55(28):4071-4074. doi: 10.1039/c9cc01081e.

MOF-templated self-polymerization of p-phenylenediamine to a polymer with a hollow box-assembled spherical structure.

Author information

1
State Key Laboratory of Chemical Resource Engineering, Beijing Key Laboratory of Electrochemical Process and Technology for Materials, Beijing University of Chemical Technology, Beijing 100029, P. R. China. songhh@mail.buct.edu.cn Jiamq@mail.buct.edu.cn.

Abstract

This paper presents the first transformation of MOFs to polymers without any additives by using a one-step MOF-templated self-polymerization approach. We investigate the conversion process and demonstrate that the MOF-templated self-polymerization is a new and effective approach for the in situ conversion of organic ligands to polymers and even carbon nanomaterials with maintained MOF configurations.

PMID:
30883629
DOI:
10.1039/c9cc01081e

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