Ternary assembly of g-C₃N₄/graphene oxide sheets /BiFeO₃ heterojunction with enhanced photoreduction of Cr(VI) under visible-light irradiation

A novel ternary composite of graphitic carbon nitride (g-C₃N₄)/graphene oxide (GO) sheets/BiFeO₃ (CNGB) with highly enhanced visible-light photocatalytic activity toward Cr(VI) photoreduction is prepared and characterized. The characterization and photocatalysis experiments corroborate its reasonable band gap, efficient charge separation and transfer, widened visible-light adsorption, easy solid-liquid separation, good stability and superior catalytic activity of CNGB. Three CNGB samples with different ratios of g-C₃N₄ and BiFeO₃ (CNGB-1, -2, -3 with 2:4, 3:3, and 4:2, respectively), though possessing different adsorption ability, eventually remove all Cr(VI) ions via photocatalysis within 90 min. The catalytic efficiency of the composite is the highest at pH 2; increases in pH decrease the catalytic ability. The inorganic anions such as SO₄^-, Cl^-, and NO₃^- only slightly affects the photocatalytic process. The matching of the band structure between BiFeO₃ and g-C₃N₄ generates efficient photogenerated electron migration from the conduction band of g-C₃N₄ to that of BiFeO₃, which is also facilitated by the electron bridging and collecting effects of GO, and holes transfer from the valence band of BiFeO₃ to that of g-C₃N₄, yielding the efficient separation of photogenerated electron-hole pairs and the subsequent enhancement of photocatalytic activity. The research provides a theoretical basis and technical support for the development of photocatalytic technologies for effective application in wastewater treatment and Cr-contaminated water restoration.