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Inorg Chem. 2018 Nov 5;57(21):13067-13070. doi: 10.1021/acs.inorgchem.8b01482. Epub 2018 Oct 17.

Biocoordination Polymer Cross-Linking Structure to a 3D Star Topology Inorganic Photocatalyst Nanocrystal with Improved Hydrogen Evolution Performance.

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School of Chemistry and Chemical Engineering, MIIT Key Laboratory of Critical Materials Technology for New Energy Conversion and Storage , Harbin Institute of Technology , Harbin 150001 , P. R. China.


An inorganic photocatalyst with a novel 3D star topology (ST) framework was obtained via multiple cross-linking of biocoordination polymers in one-step solvothermal conditions. It possessesd a large surface area (149.36 m2·g-1), among the highest value of the current reports, and represented the quantum size effect because of its 3D ST structure. The amino acid l-cysteine was introduced into the synthesis system to lead generation of the biometic coordination polymer through the amino acid dehydrate condensation and multiple cross-linking.

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