Dihalobenzoquinones are a group of disinfection byproducts with high potential toxicity and thus currently receiving increased attention. A determination method of 2,6-dichloro-1,4-benzoquinone (2,6-DCBQ) and 2,6-dibromo-1,4-benzoquinone (2,6-DBBQ) was developed upon using liquid-liquid extraction and a gas chromatography with an electronic capture detector (LLE-GC-ECD). The optimized extraction condition was as the following: volume ratio of formic acid to water 0.005%, Na2SO4 dosage 200 g L-1, methyl-tert-butyl ether (MtBE)/water volume ratio 1/10, and extraction with MtBE for once. With the dosed concentrations of 0.5-5.0 μg L-1, the recovery rates of 2,6-DCBQ and 2,6-DBBQ were 81%-88% and 73%-96%. The limits of quantitation (LOQs) of the LLE-GC-ECD method were 2.4 and 2.7 ng L-1 in 1-L water for 2,6-DCBQ and 2,6-DBBQ. In six local tap waters, 2,6-DCBQ was detected in the range of <LOQ-20.5 ng L-1 and no 2,6-DBBQ was detected. The method is recommended for low-cost and rapid determination of 2,6-DCBQ and 2,6-DBBQ in water.
Keywords: Dihalobenzoquinones; Disinfection byproducts; Drinking water; Gas chromatography.
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