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ACS Appl Mater Interfaces. 2018 Oct 24;10(42):35946-35952. doi: 10.1021/acsami.8b11405. Epub 2018 Oct 12.

Molecular Engineering of D-π-A Type of Blue-Colored Dyes for Highly Efficient Solid-State Dye-Sensitized Solar Cells through Co-Sensitization.

Author information

1
Department of Chemistry Ångstrom Laboratory, Physical Chemistry , Uppsala University , Box 523, SE-75120 Uppsala , Sweden.
2
State Key Laboratory of Fine Chemicals, Institute of Artificial Photosynthesis, DUT-KTH Joint Education and Research Centre on Molecular Devices , Dalian University of Technology , 116024 Dalian , China.

Abstract

A novel blue-colored organic donor-π-acceptor sensitizer, the so-called MKA16 dye, has been employed to construct solid-state dye-sensitized solar cells (ssDSSCs). Using 2,2',7-,7'-tetrakis( N, N-di- p-methoxyphenyl-amine) 9,9'-spirobifuorene (Spiro-OMeTAD) as hole-transport material, a good conversion efficiency of 5.8% was recorded for cells based on the MKA16 dye and a high photovoltage of 840 mV in comparison with 5.6% efficiency using the known (Dyenamo Blue) dye. By co-sensitization using the orange-colored D35 dye and MKA16 together, the solid-state solar cells showed an excellent efficiency of 7.5%, with a high photocurrent of 12.41 mA cm-2 and open-circuit voltage of 850 mV. The results show that the photocurrent of ssDSSCs can be significantly improved by co-sensitization mainly attributed to the wider light absorption range contributing to the photocurrent. In addition, results from photo-induced absorption spectroscopy show that the dye regeneration is efficient in co-sensitized solar cells. The current results possible routes of improving the design of aesthetic and highly efficient ssDSSCs.

KEYWORDS:

D-π-A dye; blue-colored dye; co-sensitization; molecular engineering; solid-state dye-sensitized solar cell

PMID:
30260625
DOI:
10.1021/acsami.8b11405

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