Effect of dissolved organic matter fractions on photodegradation of phenanthrene in ice

The effect of dissolved organic matter (DOM) fractions on photodegradation of phenanthrene (PHE) in ice was investigated. DOM in surface water and wastewater samples was fractionated using XAD-8/XAD-4 resins into five fractions: hydrophobic acid (HPO-A), hydrophobic neutral (HPO-N), transphilic acid (TPI-A), transphilic neutral (TPI-N) and hydrophilic fraction (HPI). The photodegradation rate of PHE in ice was about 40% greater than that in water. The screening effect and quenching effect contributed 3-12% and 88-97% toward the inhibition of DOM fractions on PHE photodegradation in ice, respectively. The contribution ratios of singlet oxygen (¹O₂) and hydroxyl radical (OH) produced from DOM fractions to PHE photodegradation rates in ice were 9-31% and 2-13%, respectively. Among five DOM fractions, HPO-A was most efficient in advancing PHE photodegradation in ice through ¹O₂ mechanism. When excluding the photosensitized effect of ¹O₂ and OH produced from DOM fractions, the quencing effect of DOM fractions on PHE photodegradation in ice was closely related to their PHE binding ability.