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Chem Commun (Camb). 2018 Aug 16;54(67):9294-9297. doi: 10.1039/c8cc05148h.

The perfluorinated alcohols c-C6F11OH, c-C6F10-1,1-(OH)2 and c-C6F10-1-(CF3)OH.

Author information

1
Albert-Ludwigs-Universität Freiburg, Institut für Anorganische und Analytische Chemie and Freiburger Materialforschungszentrum FMF, Albertstr. 21, D-79104 Freiburg, Germany. krossing@uni-freiburg.de.

Abstract

The thermally unstable α-fluoroalcohol undecafluorocyclohexanol (c-C6F11OH) was prepared by addition of hydrogen fluoride to the corresponding ketone. c-C6F10(CF3)OH was obtained by protonation of its alkoxide [NMe4]+[C7F13O]-. Decafluorocyclohexane-1,1-diol (c-C6F10(OH)2) was prepared by acidic workup of the corresponding alkoxide [NMe4]+[C6F11O]- with sulfuric acid, which yielded (c-C6F10(OH)2) and fluorosulfonic acid. The structures of c-C6F10(CF3)OH·2H2O and of (c-C6F10(OH)2) were elucidated by single-crystal X-ray and gas-phase electron-diffraction studies.

PMID:
30033461
DOI:
10.1039/c8cc05148h

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