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Nanoscale. 2018 Jul 13;10(27):13187-13193. doi: 10.1039/c8nr02903b.

Water-resistant PEDOT:PSS hole transport layers by incorporating a photo-crosslinking agent for high-performance perovskite and polymer solar cells.

Author information

1
Department of Chemistry and Research Institute for Convergence of Basic Sciences, Hanyang University, Seoul 04763, Republic of Korea. hschoi202@hanyang.ac.kr.

Abstract

We demonstrated a water-resistant PEDOT:PSS HTL by incorporating a photo-crosslinking agent into a PEDOT:PSS film. A crosslinking system was successfully formed inside the PEDOT:PSS film by simple and fast photo-polymerization of PCDSA monomers. Combination of the crosslinking system and MeOH surface treatment simultaneously improved the device efficiency and stability of both perovskite and polymer solar cells. The crosslinking system inside PEDOT:PSS changed its intrinsic water-soluble characteristic into a water-resistant property, thus preventing water penetration into the PEDOT:PSS film. In addition, MeOH treatment improved the surface conductivity and reduced the surface roughness of the PEDOT:PSS film by removing surface residues of PDAs and insulating PSS parts.

PMID:
29971304
DOI:
10.1039/c8nr02903b

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