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Inorg Chem. 2018 Jun 18;57(12):7113-7120. doi: 10.1021/acs.inorgchem.8b00838. Epub 2018 May 25.

Structural Mimics of the [Fe]-Hydrogenase: A Complete Set for Group VIII Metals.

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1
Division of Chemistry & Biological Chemistry , Nanyang Technological University , 21 Nanyang Link , Singapore , 637371.

Abstract

A set of structural mimics of the [Fe]-hydrogenase active site comprising all the group VIII metals, viz., [M(2-NHC(O)C5H4N)(CO)2(2-S-C5H4N)], has been synthesized. They exist as a mixture of isomers in solution, and the relative stability of the isomers depends on the nature of the metal and the substituent at the 6-position of the pyridine ligand.

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