TEGDMA and UDMA monomers released from composite dental material polymerized with diode and halogen lamps

Adv Clin Exp Med. 2018 Apr;27(4):469-476. doi: 10.17219/acem/68382.

Abstract

Background: More than 35 substances released from composite fillings have been identified. Among these, basic monomers and the so-called co-monomers are most often reported. The substances released from polymer-based materials demonstrate allergenic, cytotoxic, genotoxic, mutagenic, embryotoxic, teratogenic, and estrogenic properties.

Objectives: The aim of this study was to measure the amounts of triethylene glycol dimethacrylate (TEGDMA) and urethane dimethacrylate (UDMA) monomers released from composite dental fillings to citrate-phosphate buffer with the pH of 4, 6, 8 after 24 h and 6 months from the polymerization.

Material and methods: Ten samples for each polymerization method had been made from the composite material (Filtek Supreme XT, 3M ESPE, St. Paul, USA), which underwent polymerization using the following lamps: halogen lamp (Translux CL, Heraeus Kulzer, Hanau, Germany) (sample H) and diode lamp (Elipar Freelight 2, 3M ESPE), with soft start function (group DS) and without that function (group DWS).

Results: It has been demonstrated that the type of light-curing units has a significant impact on the amount of TEGDMA and UDMA released. The amount of UDMA and TEGDMA monomers released from composite fillings differed significantly depending on the source of polymerization applied, as well as the pH of the solution and sample storage time.

Conclusions: Elution of the monomers from composite material polymerized using halogen lamp was significantly greater as compared to curing with diode lamps.

Keywords: fluorescence spectrometry; light curing units; triethylene glycol dimethacrylate; urethane dimethacrylate.

MeSH terms

  • Bisphenol A-Glycidyl Methacrylate
  • Composite Resins / chemistry*
  • Dental Materials*
  • Halogens
  • Humans
  • Materials Testing
  • Methacrylates / chemistry*
  • Polyethylene Glycols*
  • Polymerization
  • Polymethacrylic Acids*
  • Polyurethanes*

Substances

  • Composite Resins
  • Dental Materials
  • Halogens
  • Methacrylates
  • Polymethacrylic Acids
  • Polyurethanes
  • urethane dimethacrylate luting resin
  • triethylene glycol dimethacrylate
  • Polyethylene Glycols
  • Bisphenol A-Glycidyl Methacrylate