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Nanotechnology. 2018 Apr 6;29(14):145703. doi: 10.1088/1361-6528/aaaac6.

High-performance Cu nanoparticles/three-dimensional graphene/Ni foam hybrid for catalytic and sensing applications.

Author information

1
Jiangsu Key Laboratory of Advanced Metallic Materials, School of Materials Science and Engineering, Southeast University, Nanjing 211189, People's Republic of China.

Abstract

A novel hybrid of Cu nanoparticles/three-dimensional graphene/Ni foam (Cu NPs/3DGr/NiF) was prepared by chemical vapor deposition, followed by a galvanic displacement reaction in Ni- and Cu-ion-containing salt solution through a one-step reaction. The as-prepared Cu NPs/3DGr/NiF hybrid is uniform, stable, recyclable and exhibits an extraordinarily high catalytic efficiency for the reduction of 4-nitrophenol (4-NP) to 4-aminophenol (4-AP) with a reduction rate constant K = 0.056 15 s-1, required time ∼30 s and excellent sensing properties for the non-enzymatic amperometric hydrogen peroxide (H2O2) with a linear range ∼50 μM-9.65 mM, response time ∼3 s, detection limit ∼1 μM. The results indicate that the as-prepared Cu NPs/3DGr/NiF hybrid can be used to replace expensive noble metals in catalysis and sensing applications.

PMID:
29372893
DOI:
10.1088/1361-6528/aaaac6

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