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Inorg Chem. 2017 Dec 18;56(24):14763-14766. doi: 10.1021/acs.inorgchem.7b02718. Epub 2017 Dec 4.

Two Unique Crystalline Semiconductor Zeolite Analogues Based on Indium Selenide Clusters.

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1
College of Chemistry, Chemical Engineering and Materials Science, Soochow University , Suzhou, Jiangsu 215123, China.

Abstract

Developing the structural diversity of microporous zeolitic frameworks with integrated semiconducting properties is promising but remains a challenge. Reported here are two unique crystalline semiconductor zeolite analogues constructed from two kinds of indium selenide clusters with augmented ctn and zeolite-type sod networks. The intrinsic semiconducting nature in these In-Se domains gives rise to pore-size-dependent and visible-light-driven photocatalytic activity for organic dye degradation.

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