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Environ Sci Pollut Res Int. 2018 Feb;25(4):3557-3564. doi: 10.1007/s11356-017-0706-7. Epub 2017 Nov 21.

Removal of lead from aqueous solution using polyacrylonitrile/magnetite nanofibers.

Author information

1
U.S. Pakistan Center for Advanced Studies in Water (USPCASW), Mehran University of Engineering and Technology, Jamshoro, 76062, Pakistan.
2
Nanomaterials Research Lab, Department of Textile Engineering, Mehran University of Engineering and Technology, Jamshoro, 76062, Pakistan.
3
Government Boys Degree College Qasimabad, Hyderabad, 71000, Pakistan.
4
U.S. Pakistan Center for Advanced Studies in Water (USPCASW), Mehran University of Engineering and Technology, Jamshoro, 76062, Pakistan. rbmahar.uspcasw@faculty.muet.edu.pk.

Abstract

Lead is known for its toxic and non-biodegradable behavior. The consumption of lead-contaminated water is one of the major threat the world is facing nowadays. In this study, polyacrylonitrile (PAN) and magnetite (Fe3O4) composite nanofiber adsorbent was developed for Pb2+ removal in batch mode. The synthesis was done by a simple and scalable process of electrospinning followed by chemical precipitation of Fe3O4. The nanofibers thus obtained were characterized through FTIR, zeta potential analyzer, and scanning electron microscope (SEM) and were analyzed for their adsorption capability for Pb2+ ions. The amount of metal ion adsorbed was influenced by the initial metal ion concentration, the time the adsorbent was in contact, the amount of nanofiber, and the pH of the solution. The experimental data fitted well with pseudo 2nd-order and Langmuir adsorption isotherm model. The nanofibers showed high adsorption capability and could be recommended for Pb2+ removal successfully.

KEYWORDS:

Adsorption; Electrospinning; Lead; Magnetite; Nanofibers; Pollution

PMID:
29164455
DOI:
10.1007/s11356-017-0706-7
[Indexed for MEDLINE]

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