Synthesis of nitrogen and sulfur co-doped hierarchical porous carbons and metal-free oxidative coupling of silanes with alcohols

Bingfeng Chen; Fengbo Li; Qingqing Mei; Youdi Yang; Huizhen Liu; Guoqing Yuan; Buxing Han

doi:10.1039/c7cc07931a

Synthesis of nitrogen and sulfur co-doped hierarchical porous carbons and metal-free oxidative coupling of silanes with alcohols

Chem Commun (Camb). 2017 Dec 5;53(97):13019-13022. doi: 10.1039/c7cc07931a.

Authors

Bingfeng Chen¹, Fengbo Li, Qingqing Mei, Youdi Yang, Huizhen Liu, Guoqing Yuan, Buxing Han

Affiliation

¹ Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Colloid and Interface and Thermodynamics, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190, P. R. China. hanbx@iccas.ac.cn liuhz@iccas.ac.cn.

PMID: 29164192
DOI: 10.1039/c7cc07931a

Abstract

Hierarchically porous N and S co-doped carbon was prepared by using 2,5-dihydroxy-1,4-benzoquinone as the carbon source, thiourea as the N and S source, and SiO₂ particles as the template. Using the material as the catalyst, oxidative coupling of silanes with alcohols was conducted for the first time under metal-free conditions.