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Angew Chem Int Ed Engl. 2018 Jan 8;57(2):511-515. doi: 10.1002/anie.201709420. Epub 2017 Dec 13.

A Metal-Organic Framework with Exceptional Activity for C-H Bond Amination.

Author information

1
Department of Chemistry and Biochemistry, University of California, San Diego, La Jolla, CA, 92093, USA.
2
Department of Nanoengineering, University of California, San Diego, La Jolla, CA, 92093, USA.

Abstract

The development of catalysts capable of fast, robust C-H bond amination under mild conditions is an unrealized goal despite substantial progress in the field of C-H activation in recent years. A Mn-based metal-organic framework (CPF-5) is described that promotes the direct amination of C-H bonds with exceptional activity. CPF-5 is capable of functionalizing C-H bonds in an intermolecular fashion with unrivaled catalytic stability producing >105 turnovers.

KEYWORDS:

amination; heterogeneous catalysis; manganese; metal-organic frameworks; nitrenes

PMID:
29160961
DOI:
10.1002/anie.201709420

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