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Nano Lett. 2018 Jan 10;18(1):373-380. doi: 10.1021/acs.nanolett.7b04203. Epub 2017 Nov 28.

Electron and Hole g-Factors and Spin Dynamics of Negatively Charged Excitons in CdSe/CdS Colloidal Nanoplatelets with Thick Shells.

Author information

1
Experimentelle Physik 2, Technische Universität Dortmund , 44221 Dortmund, Germany.
2
Rzhanov Institute of Semiconductor Physics, Siberian Branch of Russian Academy of Sciences , 630090 Novosibirsk, Russia.
3
Institut d'Electronique, de Microélectronique et de Nanotechnologie, CNRS , 59652 Villeneuve-d'Ascq, France.
4
Ioffe Institute, Russian Academy of Sciences , 194021 St. Petersburg, Russia.
5
State Key Laboratory of Precision Spectroscopy, East China Normal University , 200062 Shanghai, China.
6
High Field Magnet Laboratory (HFML-EMFL), Radboud University , 6525 ED Nijmegen, The Netherlands.
7
Laboratoire de Physique et d'Etude des Matériaux, ESPCI, CNRS , 75231 Paris, France.

Abstract

We address spin properties and spin dynamics of carriers and charged excitons in CdSe/CdS colloidal nanoplatelets with thick shells. Magneto-optical studies are performed by time-resolved and polarization-resolved photoluminescence, spin-flip Raman scattering and picosecond pump-probe Faraday rotation in magnetic fields up to 30 T. We show that at low temperatures the nanoplatelets are negatively charged so that their photoluminescence is dominated by radiative recombination of negatively charged excitons (trions). Electron g-factor of 1.68 is measured, and heavy-hole g-factor varying with increasing magnetic field from -0.4 to -0.7 is evaluated. Hole g-factors for two-dimensional structures are calculated for various hole confining potentials for cubic- and wurtzite lattice in CdSe core. These calculations are extended for various quantum dots and nanoplatelets based on II-VI semiconductors. We developed a magneto-optical technique for the quantitative evaluation of the nanoplatelets orientation in ensemble.

KEYWORDS:

CdSe; Nanoplatelets; core/shell nanocrystals; spin dynamics; trion

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