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Soft Matter. 2017 Nov 22;13(45):8408-8418. doi: 10.1039/c7sm01754e.

Multi-modulation for self-assemblies of amphiphilic rigid-soft compounds through alteration of solution polarity and temperature.

Author information

1
State Key Laboratory of Supramolecular Structure and Materials and College of Chemistry, Jilin University, Changchun 130012, P. R. China. wulx@jlu.edu.cn.

Abstract

A new class of small molecule-based amphiphilic carbazole-containing compounds has been designed and synthesized. Detailed analysis of the temperature- and solvent-dependent UV-vis absorption spectra has provided insights into the cooperative self-assembly mechanism of the carbazole-containing compounds. Interestingly, the prepared amphiphilic rigid-soft compounds were also found to display a lower critical solution temperature (LCST) behavior in aqueous solution, which is relatively less explored in small molecule-based materials, leading to promising candidates for the design of a new class of thermo-responsive materials.

PMID:
29077127
DOI:
10.1039/c7sm01754e

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