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ACS Appl Mater Interfaces. 2017 Aug 30;9(34):28486-28494. doi: 10.1021/acsami.7b07503. Epub 2017 Aug 15.

Investigation of the Reversible Intercalation/Deintercalation of Al into the Novel Li3VO4@C Microsphere Composite Cathode Material for Aluminum-Ion Batteries.

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State Key Laboratory of Physical Chemistry of Solid Surfaces, Collaborative Innovation Center of Chemistry for Energy Materials, State-Province Joint Engineering Laboratory of Power Source Technology for New Energy Vehicle, College of Chemistry and Chemical Engineering, Xiamen University , No. 422 Siming South Road, Xiamen, Fujian 361005, China.


The Li3VO4@C microsphere composite was first reported as a novel cathode material for rechargeable aluminum-ion batteries (AIBs), which manifests the initial discharge capacity of 137 mAh g-1 and and remains at 48 mAh g-1 after 100 cycles with almost 100% Coulombic efficiency. The detailed intercalation mechanism of Al into the orthorhombic Li3VO4 is investigated by ex situ X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS) of Li3VO4@C electrodes and the nuclear magnetic resonance aluminum spectroscopy (27Al NMR) of ionic liquid electrolytes in different discharge/charge states. First-principle calculations are also carried out to investigate the structural change as Al inserts into the framework of Li3VO4. It is revealed that the Al/Li3VO4@C battery goes through electrochemical dissolution and deposition of metallic aluminum in the anode, as well as the insertion and deinsertion of Al3+ cations in the cathode in the meantime. The rechargeable AIBs fabricated in this work are of low cost and high safety, which may make a step forward in the development of novel cathode materials based on the acidic ionic liquid electrolyte system.


Li3VO4@C; aluminum-ion battery; cathode; ionic liquid; mechanism


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