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J Org Chem. 2017 Aug 4;82(15):7695-7707. doi: 10.1021/acs.joc.7b01458. Epub 2017 Jul 24.

Indolylmethanols as Reactants in Catalytic Asymmetric Reactions.

Author information

1
School of Chemistry and Material Science, Jiangsu Normal University , Xuzhou 221116, China.

Abstract

Indolylmethanols have emerged as versatile reactants in catalytic asymmetric reactions because of the facile generation of reactive intermediates from these compounds. The most common indolylmethanols are 3-indolylmethanols and 2-indolylmethanols, and the reaction types applicable to these heterocycles mainly include catalytic enantioselective substitutions and cyclizations. Using indolylmethanols as reactants in catalytic asymmetric reactions enables the enantioselective construction of a variety of indole-containing frameworks.

PMID:
28708396
DOI:
10.1021/acs.joc.7b01458

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