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ACS Appl Mater Interfaces. 2017 Jul 19;9(28):23602-23613. doi: 10.1021/acsami.7b02104. Epub 2017 Jul 10.

Boosting Photocatalytic Performance of Inactive Rutile TiO2 Nanorods under Solar Light Irradiation: Synergistic Effect of Acid Treatment and Metal Oxide Co-catalysts.

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Division of Biotechnology, Brain Korea 21 Plus Program, Advanced Institute of Environment and Bioscience, College of Environmental and Bioresource Sciences, Chonbuk National University , Iksan, 54596, Korea.
Analytical Research Division, Korea Basic Science Institute , Jeonju, Jeollabuk-do, 54907, South Korea.
Mineral Resources Research Division, Korea Institute of Geoscience and Mineral Resources , Daejeon, 34132, Korea.


In the present work, we accomplish the boosting of photocatalytic performance by the synergistic effect of acid treatment and transition metal oxide co-catalysts on molten salt rutile TiO2 nanorods. FT-IR and XPS (oxygen deconvolution) results confirmed that the amount of hydroxyl groups increased on the surface of rutile TiO2 nanorods (TO-NRs) after acid treatment. HR-TEM analysis revealed fine dispersion of metal oxide on the surface of acid treated TiO2 nanorods (ATO-NRs). The photocatalytic activities of as-prepared (TO-NRs), acid treated (ATO-NRs), metal oxide loaded (MTO-NRs), and both acid treated and metal oxide loaded (MATO-NRs) nanorods were compared based on the rate kinetics and dye degradation efficiencies. Cobalt oxide (1 wt %) loaded and 1.0 M acid treated TiO2 nanorods (Co/ATO-NR) exhibited the higher photocatalytic degradation efficiency for Orange-II dye degradation and inactivation of S. typhimurium pathogen compared to other photocatalysts under solar irradiation. Photoelectrochemical analysis demonstrated that the charge transfer process in Co/ATO-NR is significantly higher than that in the untreated samples. The improved photocatalytic activity of inactive TO-NRs might be due to enhanced charge transfer of finely dispersed metal oxides on the OH-rich surface of acid treated TiO2 nanorods.


acid treatment; co-catalyst; dye degradation; synergistic effect; transition metal oxides


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