Format

Send to

Choose Destination
Molecules. 2017 May 20;22(5). pii: E850. doi: 10.3390/molecules22050850.

Photoreactions of Endohedral Metallofullerene with Siliranes: Electronic Properties of Carbosilylated Lu₃N@Ih-C80.

Author information

1
Department of Engineering Science, The University of Electro-Communications, Chofu 182-8585, Japan. kako@e-one.uec.ac.jp.
2
Department of Engineering Science, The University of Electro-Communications, Chofu 182-8585, Japan. minami@chemk.pc.uec.ac.jp.
3
Department of Engineering Science, The University of Electro-Communications, Chofu 182-8585, Japan. kuroiwa@chemk.pc.uec.ac.jp.
4
Department of Engineering Science, The University of Electro-Communications, Chofu 182-8585, Japan. fukazawa@chemk.pc.uec.ac.jp.
5
Department of Engineering Science, The University of Electro-Communications, Chofu 182-8585, Japan. arikawa@chemk.pc.uec.ac.jp.
6
Department of Chemistry, Tokyo Gakugei University, Tokyo 184-8501, Japan. myamada@u-gakugei.ac.jp.
7
Department of Chemistry, Tokyo Gakugei University, Tokyo 184-8501, Japan. ymaeda@u-gakugei.ac.jp.
8
Fukui Institute for Fundamental Chemistry, Kyoto University, Kyoto 606-8103, Japan. lqz1153672945@stu.xjtu.edu.cn.
9
Fukui Institute for Fundamental Chemistry, Kyoto University, Kyoto 606-8103, Japan. nagase@ims.ac.jp.
10
Department of Chemistry, Tokyo Gakugei University, Tokyo 184-8501, Japan. akasaka@tara.tsukuba.ac.jp.
11
Life Science Center of Tsukuba Advanced Research Alliance, University of Tsukuba, Ibaraki 305-8577, Japan. akasaka@tara.tsukuba.ac.jp.
12
Foundation for Advancement of International Science, Ibaraki 305-0821, Japan. akasaka@tara.tsukuba.ac.jp.
13
School of Materials Science and Engineering, Huazhong University of Science and Technology, Wuhan 430074, China. akasaka@tara.tsukuba.ac.jp.

Abstract

Photochemical carbosilylation of Lu₃N@Ih-C80 was performed using siliranes (silacyclopropanes) to afford the corresponding [5,6]- and [6,6]-adducts. Electrochemical studies indicated that the redox potentials of the carbosilylated derivatives were shifted cathodically in comparison with those of the [5,6]-pyrrolidino adducts. The electronic effect of the silirane addends on Lu₃N@Ih-C80 was verified on the basis of density functional theory calculations.

KEYWORDS:

Lu3N@Ih-C80; carbosilylation; endohedral metallofullerene; redox property; silirane

PMID:
28531116
PMCID:
PMC6154294
DOI:
10.3390/molecules22050850
[Indexed for MEDLINE]
Free PMC Article

Supplemental Content

Full text links

Icon for Multidisciplinary Digital Publishing Institute (MDPI) Icon for PubMed Central
Loading ...
Support Center