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ACS Appl Mater Interfaces. 2017 Mar 29;9(12):10360-10365. doi: 10.1021/acsami.7b00181. Epub 2017 Mar 16.

Uniform Lithium Deposition Induced by Polyacrylonitrile Submicron Fiber Array for Stable Lithium Metal Anode.

Author information

1
The State Key Lab of New Ceramic and Fine Processing, School of Materials Science and Engineering, Tsinghua University , Beijing 100084, China.
2
School of Materials Science and Engineering, University of Science and Technology Beijing , Beijing 100084, China.

Abstract

The lithium dendrite growth and low Coulombic efficiency (CE) during lithium plating/striping cycles are the main obstacles for practical applications of lithium metal anode. Herein, we demonstrate that polyacrylonitrile (PAN) submicron fiber array could guide the lithium ions to uniformly disperse and deposit onto current collector. The PAN submicron fiber array nearly does not increase the volume of electrode with ultralow mass. By this simple design, we achieved stable cycling of lithium metal anode with an average CE of ∼97.4% for 250 cycles at a current density of 1 mA cm-2 with total Li capacity of 1 mAh cm-2.

KEYWORDS:

draw-spinning; fiber array; lithium metal battery; polyacrylonitrile; stable cycling performance

PMID:
28291328
DOI:
10.1021/acsami.7b00181

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