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Chem Commun (Camb). 2017 Mar 2;53(19):2858-2861. doi: 10.1039/c6cc10139a.

σ-Complexation as a strategy for designing copper-based light emitters.

Author information

1
Department of Chemistry, KAIST, Daejeon 34141, Republic of Korea. yunholee@kaist.ac.kr.

Abstract

Strongly emissive cuprous complexes containing a stable σ-SiH-Cu motif were prepared. These complexes serve as a proof of principle that σ-complexation can be utilized as a design principle for engineering responsive light emitting materials. Their excited state lifetimes were found to be long (∼20 μs) with high quantum yields (φ = 0.40-0.59).

PMID:
28217781
DOI:
10.1039/c6cc10139a

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