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Chem Commun (Camb). 2017 Feb 23;53(17):2598-2601. doi: 10.1039/c6cc10005h.

Dual role of Cu2O nanocubes as templates and networking catalysts for hollow and microporous Fe-porphyrin networks.

Author information

1
Department of Chemistry, Sungkyunkwan University, Suwon 16419, Korea. sson@skku.edu.
2
Korea Basic Science Institute, Daejeon 350-333, Korea.
3
Laboratory of Nuclear Magnetic Resonance, National Center for Inter-University Research Facilities (NCIRF), Seoul National University, Seoul 08826, Korea.
4
Department of Chemistry, Pusan National University, Busan 46241, Korea.

Abstract

Cu2O nanocubes were used for the synthesis of hollow and microporous Fe porphyrin networks (H-MFePN). In this synthesis, Cu2O nanocubes performed not only as networking catalysts but also as shape controlling templates. MFePN were formed on the surface of the Cu2O nanocubes through azide-alkyne cycloaddition of tetrakis(4-ethynylphenyl) Fe-porphyrin with 1,4-diazidobenzene. H-MFePN showed excellent catalytic activities in carbene insertion into N-H bonds, maintaining their activities during five recycle tests.

PMID:
28191560
DOI:
10.1039/c6cc10005h

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