Format

Send to

Choose Destination
J Am Chem Soc. 2017 Feb 8;139(5):1958-1966. doi: 10.1021/jacs.6b11612. Epub 2017 Jan 24.

New Wide Band Gap Donor for Efficient Fullerene-Free All-Small-Molecule Organic Solar Cells.

Yang L1,2, Zhang S1,3, He C1,2, Zhang J2,4, Yao H1,2, Yang Y4, Zhang Y1,2, Zhao W1,2, Hou J1,2.

Author information

1
Beijing National Laboratory for Molecular Sciences, State Key Laboratory of Polymer Physics and Chemistry, Institute of Chemistry, Chinese Academy of Sciences , Beijing 100190, China.
2
University of Chinese Academy of Sciences , Beijing 100049, China.
3
School of Chemistry and Biology Engineering, University of Science and Technology Beijing , Beijing 100083, China.
4
Key Laboratory of Nanosystem and Hierarchical Fabrication, National Center for Nanoscience and Technology , Beijing 100190, China.

Abstract

A new organic small molecule, DRTB-T, that incorporates a two-dimensional trialkylthienyl-substituted benzodithiophene core building block was designed and synthesized. DRTB-T has a band gap (Egopt) of 2.0 eV with a low-lying highest occupied molecular orbital (HOMO) level of -5.51 eV. Nonfullerene small-molecule solar cells consisting of DRTB-T and a nonfullerene acceptor (IC-C6IDT-IC) were constructed, and the morphology of the active layer was fine-tuned by solvent vapor annealing (SVA). The device showed a record 9.08% power conversion efficiency (PCE) with a high open-circuit voltage (Voc = 0.98 V). This is the highest PCE for a nonfullerene small-molecule organic solar cell (NFSM-OSC) reported to date. Our notable results demonstrate that the molecular design of a wide band gap (WBG) donor to create a well-matched donor-acceptor pair with a low band gap (LBG) nonfullerene small-molecule acceptor, as well as subtle morphological control, provides great potential to realize high-performance NFSM-OSCs.

PMID:
28081597
DOI:
10.1021/jacs.6b11612

Supplemental Content

Full text links

Icon for American Chemical Society
Loading ...
Support Center