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Inorg Chem. 2016 Dec 19;55(24):12492-12495. Epub 2016 Nov 29.

Elaboration of a Highly Porous RuII,II Analogue of HKUST-1.

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Lehrstuhl für Anorganische Chemie II, Organometallics & Materials, Ruhr-Universität , Bochum, Germany.
Department of Chemistry, Technical University Munich , Lichtenbergstrasse 4, D-85748 Garching, Germany.


When the dinuclear RuII,II precursor [Ru2(OOCCH3)4] is employed under redox-inert conditions, a RuII,II analogue of HKUST-1 was successfully prepared and characterized as a phase-pure microcrystalline powder. X-ray absorption near-edge spectroscopy confirms the oxidation state of the Ru centers of the paddle-wheel nodes in the framework. The porosity of 1371 m2/mmol of RuII,II-HKUST-1 exceeds that of the parent compound HKUST1 (1049 m2/ mmol).

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