Synthesis of Penta-2,4-dien-1-imines and 1,2-Dihydropyridines by Rhodium-Catalyzed Reaction of N-Sulfonyl-1,2,3-triazoles with 2-(Siloxy)furans

Yuuta Funakoshi; Tomoya Miura; Masahiro Murakami

doi:10.1021/acs.orglett.6b03143

Synthesis of Penta-2,4-dien-1-imines and 1,2-Dihydropyridines by Rhodium-Catalyzed Reaction of N-Sulfonyl-1,2,3-triazoles with 2-(Siloxy)furans

Org Lett. 2016 Dec 16;18(24):6284-6287. doi: 10.1021/acs.orglett.6b03143. Epub 2016 Nov 28.

Authors

Yuuta Funakoshi¹, Tomoya Miura¹, Masahiro Murakami¹

Affiliation

¹ Department of Synthetic Chemistry and Biological Chemistry, Kyoto University , Katsura, Kyoto 615-8510, Japan.

PMID: 27978682
DOI: 10.1021/acs.orglett.6b03143

Abstract

A rhodium(II)-catalyzed reaction of N-sulfonyl-1,2,3-triazoles with 2-(siloxy)furans is reported. Either open-chain penta-2,4-dien-1-imines or cyclic 1,2-dihydropyridines are selectively obtained depending on the ligand on rhodium(II).

Publication types

Research Support, Non-U.S. Gov't