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Chem Commun (Camb). 2016 Dec 20;53(1):172-175.

Multiphase transition of supramolecular metallogels triggered by temperature.

Author information

1
Shanghai Key Laboratory of Green Chemistry and Chemical Processes, School of Chemistry and Molecular Engineering, East China Normal University, 3663 N. Zhongshan Road, Shanghai, China. hbyang@chem.ecnu.edu.cn 51113300008@ecnu.cn.

Abstract

We present a new family of supramolecular metallogels undergoing reversible multiphase transition triggered by temperature from amphiphilic alkynylplatinum(ii) complexes. Further investigation revealed that intermolecular PtPt and π-π stacking interactions facilitate such phase transitions upon increasing the temperature.

PMID:
27910973
DOI:
10.1039/c6cc08382j

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