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Angew Chem Int Ed Engl. 2016 Dec 23;55(52):16123-16126. doi: 10.1002/anie.201609049. Epub 2016 Nov 25.

Cost-Effective, High-Performance Porous-Organic-Polymer Conductors Functionalized with Sulfonic Acid Groups by Direct Postsynthetic Substitution.

Author information

1
Department of Chemistry, Korea University, Seoul, 136-713, Korea.
2
Fuel Cell Research Center, Korea Institute of Science and Technology, 5, Hwarang-ro 14-gil, Seongbuk-gu, Seoul, 02792, Republic of Korea.

Abstract

We demonstrate the facile microwave-assisted synthesis of a porous organic framework 1 and the sulfonated solid (1S) through postsubstitution. Remarkably, the conductivity of 1S showed an approximately 300-fold enhancement at 30 °C as compared to that of 1, and reached 7.72×10-2  S cm-1 at 80 °C and 90 % relative humidity. The superprotonic conductivity exceeds that observed for any conductive porous organic polymer reported to date. This material, which is cost-effective and scalable for mass production, also revealed long-term performance over more than 3 months without conductivity decay.

KEYWORDS:

long-term performance; microwave chemistry; porous organic polymers; postsynthetic substitution; proton-conducting materials

PMID:
27885758
DOI:
10.1002/anie.201609049

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