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J Chem Phys. 2016 Sep 14;145(10):104901. doi: 10.1063/1.4962196.

Relaxation dynamics of multilayer triangular Husimi cacti.

Author information

1
Departamento de FĂ­sica, Universidade Federal do Amazonas, 69077-000 Manaus, Brazil.
2
Department of Condensed Matter Physics and Advanced Technologies, Faculty of Physics, Babes-Bolyai University, Street Mihail Kogalniceanu 1, 400084 Cluj-Napoca, Romania.

Abstract

We focus on the relaxation dynamics of multilayer polymer structures having, as underlying topology, the Husimi cactus. The relaxation dynamics of the multilayer structures is investigated in the framework of generalized Gaussian structures model using both Rouse and Zimm approaches. In the Rouse type-approach, we determine analytically the complete eigenvalues spectrum and based on it we calculate the mechanical relaxation moduli (storage and loss modulus) and the average monomer displacement. First, we monitor these physical quantities for structures with a fixed generation number and we increase the number of layers, such that the linear topology will smoothly come into play. Second, we keep constant the size of the structures, varying simultaneously two parameters: the generation number of the main layer, G, and the number of layers, c. This fact allows us to study in detail the crossover from a pure Husimi cactus behavior to a predominately linear chain behavior. The most interesting situation is found when the two limiting topologies cancel each other. For this case, we encounter in the intermediate frequency/time domain regions of constant slope for different values of the parameter set (G, c) and we show that the number of layers follows an exponential-law of G. In the Zimm-type approach, which includes the hydrodynamic interactions, the quantities that describe the mechanical relaxation dynamics do not show scaling behavior as in the Rouse model, except the limiting case, namely, a very high number of layers and low generation number.

PMID:
27634273
DOI:
10.1063/1.4962196

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