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Adv Mater. 2016 Oct;28(39):8705-8711. doi: 10.1002/adma.201602338. Epub 2016 Aug 16.

Selective Adsorption of Sulfur Dioxide in a Robust Metal-Organic Framework Material.

Author information

1
School of Chemistry, University of Manchester, Manchester, M13 9PL, UK.
2
The Chemical and Engineering Materials Division (CEMD), Neutron Sciences Directorate, Oak Ridge National Laboratory, Oak Ridge, TN, 37831, USA.
3
School of Chemistry, Cardiff University, Cardiff, CF10 3XQ, UK.
4
School of Chemistry, University of Nottingham, University Park, Nottingham, NG7 2RD, UK.
5
Diamond Light Source, Harwell Science Campus, Oxfordshire, OX11 0DE, UK.
6
College of Chemistry and Molecular Engineering, Peking University, Beijing, 100871, China.
7
ISIS Neutron & Muon Source, STFC Rutherford Appleton Laboratory, Chilton, Oxfordshire, OX11 0QX, UK.
8
Hiden Isochema, 422 Europa Boulevard, Warrington, WA5 7TS, UK.
9
European Synchrotron Radiation Facility, Grenoble, 38043, France.
10
School of Chemistry, University of Manchester, Manchester, M13 9PL, UK. Sihai.Yang@manchester.ac.uk.
11
School of Chemistry, University of Manchester, Manchester, M13 9PL, UK. M.Schroder@manchester.ac.uk.

Abstract

Selective adsorption of SO2 is realized in a porous metal-organic framework material, and in-depth structural and spectroscopic investigations using X-rays, infrared, and neutrons define the underlying interactions that cause SO2 to bind more strongly than CO2 and N2 .

KEYWORDS:

carbon dioxide; carboxylates; indium; metal-organic frameworks; sulfur dioxide

PMID:
27529671
DOI:
10.1002/adma.201602338

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