Format

Send to

Choose Destination
ACS Appl Mater Interfaces. 2016 Aug 31;8(34):22168-74. doi: 10.1021/acsami.6b05594. Epub 2016 Aug 22.

Effects of Carbon Content on the Electrochemical Performances of MoS2-C Nanocomposites for Li-Ion Batteries.

Author information

1
Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), College of Chemistry; Nankai University , Tianjin 300071, China.
2
Department of Energy and Materials Engineering, Dongguk University-Seoul , Seoul 100-715, Republic of Korea.

Abstract

Molybdenum disulfide is popular for rechargeable batteries, especially in Li-ion batteries, because of its layered structure and relatively high specific capacity. In this paper, we report MoS2-C nanocomposites that are synthesized by a hydrothermal process, and their use as anode material for Li-ion batteries. Ascorbic acid is used as the carbon source, and the carbon contents can be tuned from 2.5 wt % to 16.2 wt %. With increasing of carbon content, the morphology of MoS2-C nanocomposites changes from nanoflowers to nanospheres, and the particle size is decreased from 200 to 60 nm. This change is caused by the chemical complex interaction of ascorbic acid. The MoS2-C nanocomposite with 8.4 wt % C features a high capacity of 970 mAh g(-1) and sustains a capacity retention ratio of nearly 100% after 100 cycles. When the current increases to 1000 mA g(-1), the capacity still reaches 730 mAh g(-1). The above manifests that the carbon coating layer does not only accelerate the charge transfer kinetics to supply quick discharging and charging, but also hold the integrity of the electrode materials as evidenced by the long cycling stability. Therefore, MoS2-based nanocomposites could be used as commercial anode materials in Li-ion batteries.

KEYWORDS:

Li-ion batteries; MoS2; anode; effect of carbon content; stability

PMID:
27502442
DOI:
10.1021/acsami.6b05594

Supplemental Content

Full text links

Icon for American Chemical Society
Loading ...
Support Center