Send to

Choose Destination
J Am Chem Soc. 2016 Aug 3;138(30):9385-8. doi: 10.1021/jacs.6b05341. Epub 2016 Jul 22.

Plating a Dendrite-Free Lithium Anode with a Polymer/Ceramic/Polymer Sandwich Electrolyte.

Author information

Materials Science and Engineering Program & Texas Materials Institute, The University of Texas at Austin , Austin, Texas 78712, United States.


A cross-linked polymer containing pendant molecules attached to the polymer framework is shown to form flexible and low-cost membranes, to be a solid Li(+) electrolyte up to 270 °C, much higher than those based on poly(ethylene oxide), to be wetted by a metallic lithium anode, and to be not decomposed by the metallic anode if the anions of the salt are blocked by a ceramic electrolyte in a polymer/ceramic membrane/polymer sandwich electrolyte (PCPSE). In this sandwich architecture, the double-layer electric field at the Li/polymer interface is reduced due to the blocked salt anion transfer. The polymer layer adheres/wets the lithium metal surface and makes the Li-ion flux at the interface more homogeneous. This structure integrates the advantages of the ceramic and polymer. With the PCPSE, all-solid-state Li/LiFePO4 cells showed a notably high Coulombic efficiency of 99.8-100% over 640 cycles.


Supplemental Content

Full text links

Icon for American Chemical Society
Loading ...
Support Center