Electrical Behavior of Copper Mine Tailings During EKR with Modified Electric Fields

Bull Environ Contam Toxicol. 2017 Mar;98(3):304-309. doi: 10.1007/s00128-016-1858-8. Epub 2016 Jun 21.

Abstract

Electro-kinetic remediation (EKR) with sinusoidal electric field obtained simultaneously with DC/AC voltage reduce the polarization of the EKR with DC voltage. The DC voltage value defines the presence of a periodic polarity reversal of the cell and the electrical charge for electro-kinetic transport. In this case, the AC frequency favors the breaking of polarization conditions resulting from the EKR with DC voltage. However, with high frequencies a negative effect occurs where the tailings behave as a filter circuit, discriminating frequencies of an electric signal. The goal of this work is to analyse the electrical behaviour of tailings in EKR experiments. The conditions selected were: DC/AC voltages: 10/15 and 20/25 V (peak values), and AC voltage frequencies 50-2000 Hz. When the AC frequency reaches 2000 Hz, the copper removal tends to zero, indicating that the tailing behaves as a high-pass filter in which the DC voltage was filtered out.

Keywords: Electro-remediation; Filter circuit; Mine tailings; Sinusoidal electric field.

MeSH terms

  • Copper / chemistry*
  • Copper / isolation & purification*
  • Electricity*
  • Environmental Restoration and Remediation / methods*
  • Kinetics
  • Mining*
  • Soil / chemistry*

Substances

  • Soil
  • Copper