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Org Lett. 2016 Jun 17;18(12):2812-5. doi: 10.1021/acs.orglett.6b01032. Epub 2016 Jun 7.

Access to Structurally Diverse Quinoline-Fused Heterocycles via Rhodium(III)-Catalyzed C-C/C-N Coupling of Bifunctional Substrates.

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1
Dalian Institute of Chemical Physics, Chinese Academy of Sciences , Dalian 116023, China.

Abstract

Rhodium(III)-catalyzed C-H activation of heteroarenes and functionalization with bifunctional substrates such as anthranils allows facile construction of quinoline-fused heterocycles under redox-neutral conditions. The couplings feature broad substrate scope and provide step-economical access to two classes of quinoline-fused condensed heterocycles.

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