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Chem Commun (Camb). 2016 Jun 28;52(51):7978-81. doi: 10.1039/c6cc03497g. Epub 2016 Jun 2.

Cuboctahedron-based indium-organic frameworks for gas sorption and selective cation exchange.

Author information

1
College of Chemistry and Materials Engineering, Wenzhou University, Wenzhou 325035, P. R. China. jinjieqian@wzu.edu.cn smhuang@wzu.edu.cn.

Abstract

[Me2NH2]3[In3(BTB)4]·2DMF·2DMA·28H2O (InOF-9) is an anionic indium-organic framework based on nanosized cuboctahedrons, which is sustained by tetrahedral [In(COO)4] nodes and 3-connected tricarboxylates. Although InOF-9 is structurally unstable when exposed to air, it exhibits excellent gas sorption capacity through a supercritical carbon dioxide activation process and selectively encapsulates guest methylene blue cations.

PMID:
27254101
DOI:
10.1039/c6cc03497g

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