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Dalton Trans. 2016 May 17;45(20):8637-44. doi: 10.1039/c6dt01179a.

Ambient pressure synthesis of MIL-100(Fe) MOF from homogeneous solution using a redox pathway.

Author information

1
Department of Thermally Active Materials and Solar Cooling, Fraunhofer Institute for Solar Energy Systems (ISE), Heidenhofstr. 2, D-79110 Freiburg, Germany. stefan.henninger@ise.fraunhofer.de and Institut für Anorganische Chemie und Strukturchemie, Universität Düsseldorf, Universitätsstr. 1, D-40225 Düsseldorf, Germany. janiak@uni-duesseldorf.de.
2
Department of Thermally Active Materials and Solar Cooling, Fraunhofer Institute for Solar Energy Systems (ISE), Heidenhofstr. 2, D-79110 Freiburg, Germany. stefan.henninger@ise.fraunhofer.de.
3
Institut für Anorganische Chemie und Strukturchemie, Universität Düsseldorf, Universitätsstr. 1, D-40225 Düsseldorf, Germany. janiak@uni-duesseldorf.de.

Abstract

Micro- to mesoporous iron(iii) trimesate MIL-100(Fe) is a MOF of high interest for numerous applications. With regard to large-scale synthesis, e.g., by continuous flow or the in situ deposition of coatings, a replacement for the conventional, hydrothermal low-yield fluoride-containing synthesis is desirable. In this contribution, we present a method to synthesize crystalline fluoride-free MIL-100(Fe) from iron(iii) nitrate and trimesic acid in zeotropic DMSO/water solution at normal ambient pressure involving a DMSO-nitrate redox pathway. Yields of 72%, surface areas of SBET = 1791 m(2) g(-1) and pore volumes of Vpore = 0.82 cm(3) g(-1) were achieved.

PMID:
27143562
DOI:
10.1039/c6dt01179a

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